On the feasibility of unlicensed communications in the TV white space: Field measurements in the UHF band

In practical unlicensed communications in TV band, radio devices have to identify, at first, the transmission opportunities, that is, the portion of the spectrum licensed for broadcasting services unoccupied in a certain region at certain time, that is, the so-called TV white space. In this paper the outcome of field measurements in the UHF TV band (470-860 MHz) conducted in EU is presented. To obtain empirical values for the parameters upon which unlicensed radio devices are able to distinguish in a real scenario between empty and occupied TV channels, signal power measurements have been performed in Italy, Spain, and Romania on rural, suburban, and urban sites, at different heights over the ground by using different analysis bandwidths. The aim of this work is to provide a set of practical parameters upon which harmless unlicensed communication in the UHF TV white space is feasible. The results have been analyzed with respect to the hidden node margin problem, spectrum sensing bandwidth, and occupancy threshold

Bromido(dodecafluorosubphthalo­cyaninato)boron(III)

The title compound, C24BBrF12N6 or Br-F12BsubPc (BsubPc is boronsubphtalocyanine), has a bowl-shaped structure with an approximate mol­ecular C 3v symmetry characteristic of boronsubphthalocyanine compounds. In the crystal, mol­ecules are arranged in one-dimensional columns and the boron–subphthalocyanine units within each column are offset and angled in a bowl-to-ligand packing arrangement such that the axial Br atom rests in the aromatic concaved bowl of the neighboring subphthalocyanine with an inter­molecular Br⋯B distance of 3.721 (3) Å

Phthalocyanine-nanocarbon ensembles: From discrete molecular and supramolecular systems to hybrid nanomaterials

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Accounts of Chemical Research, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ar5004384Conspectus Phthalocyanines (Pcs) are macrocyclic and aromatic compounds that present unique electronic features such as high molar absorption coefficients, rich redox chemistry, and photoinduced energy/electron transfer abilities that can be modulated as a function of the electronic character of their counterparts in donor-acceptor (D-A) ensembles. In this context, carbon nanostructures such as fullerenes, carbon nanotubes (CNTs), and, more recently, graphene are among the most suitable Pc companions. Pc-C60 ensembles have been for a long time the main actors in this field, due to the commercial availability of C60 and the ell-established synthetic methods for its functionalization. As a result, many Pc-C60 architectures have been prepared, featuring different connectivities (covalent or supramolecular), intermolecular interactions (self-organized or molecularly dispersed species), and Pc HOMO/LUMO levels. All these elements provide a versatile toolbox for tuning the photophysical properties in terms of the type of process (photoinduced energy/electron transfer), the nature of the interactions beteen the electroactive units (through bond or space), and the kinetics of the formation/decay of the photogenerated species. Some recent trends in this field include the preparation of stimuli-responsive multicomponent systems ith tunable photophysical properties and highly ordered nanoarchitectures and surface-supported systems shoing high charge mobilities. A breakthrough in the Pc-nanocarbon field as the appearance of CNTs and graphene, hich opened a ne avenue for the preparation of intriguing photoresponsive hybrid ensembles shoing light-stimulated charge separation. The scarce solubility of these 1-D and 2-D nanocarbons, together ith their loer reactivity ith respect to C60 stemming from their less strained sp2 carbon netorks, has not meant an unsurmountable limitation for the preparation of variety of Pc-based hybrids. These systems, hich sho improved solubility and dispersibility features, bring together the unique electronic transport properties of CNTs and graphene ith the excellent light-harvesting and tunable redox properties of Pcs. A singular and distinctive feature of these Pc-CNT/graphene (single- or fe-layers) hybrid materials is the control of the direction of the photoinduced charge transfer as a result of the band-like electronic structure of these carbon nanoforms and the adjustable electronic levels of Pcs. Moreover, these conjugates present intensified light-harvesting capabilities resulting from the grafting of several chromophores on the same nanocarbon platform.In this Account, recent progress in the construction of covalent and supramolecular Pc-nanocarbon ensembles is summarized, ith a particular emphasis on their photoinduced behavior. e believe that the high degree of control achieved in the preparation of Pc-carbon nanostructures, together ith the increasing knoledge of the factors governing their photophysics, ill allo for the design of next-generation light-fueled electroactive systems. Possible implementation of these Pc-nanocarbons in high performance devices is envisioned, finally turning into reality much of the expectations generated by these materialsFinancial support from the Spanish MICINN (CTQ2011-24187/BQU), the Comunidad de Madrid (S2013/MIT-2841 FOTOCARBON) and the EU (“SO2S” FP7-PEOPLE-2012-ITN, no.: 316975) is acknowledge

Zinc Phthalocyanine−Graphene Hybrid Material for Energy Conversion: Synthesis, Characterization, Photophysics and Photoelectrochemical Cell Preparation

Graphene exfoliation upon tip sonication in o-­‐DCB was accomplished. Then, covalent grafting of (2-­‐ aminoethoxy)(tri-­‐tert-­‐butyl) zinc phthalocyanine (ZnPc), to exfoliated graphene sheets was achieved. The newly formed ZnPc-­‐graphene hybrid material was found soluble in common organic solvents without any precipitation for several weeks. Application of diverse spectroscopic techniques verified the successful formation of ZnPc-­‐graphene hybrid materi-­‐ al, while thermogravimetric analysis revealed the amount of ZnPc loading onto graphene. Microscopy analysis based on AFM and TEM was applied to probe the morphological characteristics and to investigate the exfoliation of graphene sheets. Efficient fluorescence quenching of ZnPc in the ZnPc-­‐graphene hybrid material suggested that photoinduced events occur from the photoexcited ZnPc to exfoliated graphene. The dynamics of the photoinduced electron transfer was evaluated by femtosecond transient absorption spectroscopy, thus, revealing the formation of transient species such as ZnPc+ yielding the charge-­‐separated state ZnPc•+–graphene•–. Finally, the ZnPc-­‐graphene hybrid material was integrated into a photoactive electrode of an optical transparent electrode (OTE) cast with nanostructured SnO2 films (OTE/SnO2), which exhibited sta le and reproducible photocurrent responses and the incident photon-­‐to-­‐current conversion efficien-­‐ cy was determine

Heuristic performance evaluation for DVB-T/T2 SFN network

In DVB-T/T2 broadcasting single frequency network (SFN) multipath interference (MPI) at the receiver antenna is a critical issue. The capability to elaborate those signals depends on both synchronization strategy used and coded orthogonal frequency-division multiplexing (COFDM) modulation properties. An efficient COFDM system requires the guard interval as short as possible and such as to protect the system from the MPI. To cope with this problem a static delay adjustment obtained by fitting the launching time of each broadcast station is introduced so that the time difference of the incoming signals within the reception area falls into the COFDM guard interval. This work investigates the use of advanced simulated annealing to optimize transmission parameters such as the static delay, gain and orientation of sector antennas of DVB-T/T2 transmitters in SFNs. In particular, we identify the static delay adjustment map to maximize the coverage area according to quality of service requirements. The proposed approach has been validated for DVB-T/T2 network planning in the Basque Country (Spain) and Sardinia island (Italy). Different density of transmitters, generalized geography of territory are considered for the best setting of the parameters involved. Reliability studies are included to demonstrate the efficacy of the method

Field measurements for practical unlicensed communication in the UHF band

This paper presents the result of a measurement campaign conducted in Italy, Spain, and Romania to obtain empirical values for the parameters upon which unlicensed devices could distinguish in a hidden node scenario between empty and occupied TV channels. Signal power measurements in the UHF frequency band (470–860 MHz) have been carried out on rural, sub-urban, and urban sites, at different heights over the ground by using different analysis bandwidths. The results have been analyzed with respect to the hidden node margin problem, spectrum sensing bandwidth, and occupancy threshold, to produce a set of practical parameters upon which harmless unlicensed communication in the UHF TV bands is feasible